Site-specific introduction of gold-carbenoids by intermolecular oxidation of ynamides or ynol ethers.
نویسندگان
چکیده
Ynamides and ynol ethers undergo intermolecular gold-catalysed reaction with a nucleophilic oxidant to access metal-carbenoid reactivity patterns. A site-specific oxidation/1,2-insertion cascade is used for a general access to functionalised α,β-unsaturated carboxylic acid derivatives and vinylogous carbimates.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 47 1 شماره
صفحات -
تاریخ انتشار 2011